Can any one tell me about the running of protoolkit in pro-e
The question is a little unclear about where you want to start exactly, however, I can recommend that you start by looking in to the Protoolkit directory inside your Wildfire install directory. There are a lot of examples in the subfolders.
I am not sure, but you may have to reconfigure proe using ptcsetup.bat so that you install the pro/TOOLKIT option before the files are available.
I have provided the PDFs (not all the files) for you here.